- Product Name2-NITROPROPENE
- cas4749-28-4
- purity99%
Others
Top Quality 2-NITROPROPENE 4749-28-4 Hot Sell In Stock
- Molecular Formula:C3H5 N O2
- Molecular Weight:87.0782
- Vapor Pressure:19.1mmHg at 25°C
- Melting Point:65-67 °C
- Refractive Index:1.4358
- Boiling Point:119.4°Cat760mmHg
- Flash Point:31.9°C
- PSA：45.82000
- Density:1.015g/cm3
- LogP:1.31990
2-NITROPROPENE(Cas 4749-28-4) Usage
|
Safety Profile |
Potentially dangerouspolymerization reaction on contact with alkalies. Whenheated to decomposition it emits toxic fumes of NOx. Seealso NITROALKANES. |
InChI:InChI=1/C3H5NO2/c1-3(2)4(5)6/h1H2,2H3
4749-28-4 Relevant articles
Organocatalytic Enantioselective Michael-Aldol[3+2] Annulation for the Synthesis of Nitro-Methanobenzo[7] annulenes
Liu, Jin-Yu,Zhang, Xiao-Hai,Zhang, Yang
supporting information, p. 5008 - 5011 (2021/09/28)
We report an enantioselective Michael-Al...
Access to C5-Alkylated Indolines/Indoles via Michael-Type Friedel-Crafts Alkylation Using Aryl-Nitroolefins
Ertugrul, Berrak,Kilic, Haydar,Lafzi, Farrokh,Saracoglu, Nurullah
, p. 9018 - 9038 (2018/06/27)
A straightforward synthetic route toward...
Construction of multisubstituted tetrahydropyrans by a domino oxa-michael/tsujia-trost reaction
Wang, Liang,Menche, Dirk
, p. 10811 - 10823 (2013/02/22)
Biologically significant tetrahydropyran...
Unexpected course of [2+3] cycloaddition of 2-nitropropene to (Z)-C,N-diphenylnitrone
Jasinski, Radomir,Mikulska, Maria,Baranski, Andrzej
body text, p. 41 - 45 (2012/04/23)
The [2+3] cycloaddition of 2-nitropropen...
4749-28-4 Process route
-
-
2902-96-7
2-NITROPROPANOL
-
-
4749-28-4
2-nitropropene
Conditions
| Conditions | Yield |
|---|---|
|
With
phthalic anhydride;
Heating;
|
94% |
|
With
phthalic anhydride;
at 150 - 185 ℃;
for 1.5h;
|
72% |
|
With
triethylamine; trifluoroacetic anhydride;
Inert atmosphere;
|
56% |
|
With
phthalic anhydride;
at 150 - 200 ℃;
|
51% |
|
With
dicyclohexyl-carbodiimide;
copper(l) chloride;
In
diethyl ether;
at 35 ℃;
for 3.5h;
|
45% |
|
With
phthalic anhydride;
at 175 - 180 ℃;
under 80 Torr;
|
|
|
With
phthalic anhydride;
|
|
|
at 270 ℃;
under 98 Torr;
Further Variations:;
Pressures;
Temperatures;
also in the presence of free radical inhibitors;
Kinetics;
|
|
|
With
phthalic anhydride;
|
-
-
4749-28-4
2-nitropropene
Conditions
| Conditions | Yield |
|---|---|
|
With
calcium magnesium phosphate;
at 285 ℃;
|
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